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38218-24-5

38218-24-5 structure
38218-24-5 structure

Name Indium tri(2-propanolate)
Synonyms MFCD00210318
Description Indium(III) Isopropoxide is an organo-metallic compound. Indium(III) Isopropoxide uesd as a hydrogen transfer catalyst for conversion of benzylic alcohols into aldehydes or ketones via Oppenauer oxidation. Indium(III) Isopropoxide also can be used as metal precursor[1][2].
Related Catalog
In Vitro Indium(III) isopropoxide as an Oppenauer­oxidation catalyst, and the conversion of primary or secondary alcohols into the corresponding aldehydes or ketones was promoted at room temperature using pivalaldehyde as an oxidant[1].
References

[1]. Yohei Ogiwara, et al. Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation. Synthesis. 2016, 48(23): 4143-4148.

[2]. Daniela Caruntu, et al. One-Step Synthesis of Nearly Monodisperse, Variable-Shaped In 2 O 3 Nanocrystals in Long Chain Alcohol Solutions. The Journal of Physical Chemistry C. March 2010, 114(11):4875-4886.

Density 0.808 g/mL at 25ºC
Boiling Point 82℃
Melting Point 145ºC (dec.)
Molecular Formula C3H8O.1/3In
Molecular Weight 292.07900
Flash Point 10ºC
Exact Mass 292.05300
PSA 69.18000
LogP 2.47590
Index of Refraction n20/D1.383
Water Solubility Soluble in alcohols, ketones and esters.
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H319-H336
Precautionary Statements P210-P261-P305 + P351 + P338
Hazard Codes F: Flammable;Xi: Irritant;
Risk Phrases 36/37/38-41-11
Safety Phrases 26-36/37/39-36-33-16
RIDADR UN 1219 3/PG 2