Methyl 4-bromobenzoate

Names

[ CAS No. ]:
619-42-1

[ Name ]:
Methyl 4-bromobenzoate

[Synonym ]:
EINECS 210-596-6
F3095-4305
4-Bromobenzoic Acid Methyl Ester
Benzoic acid,4-bromo-,methyl ester
p-Br(C6H4)CO2Me
methyl 4-bromobenzoate (4-bromobenzoic acid methyl ester)
Methyl-4-brombenzolcarboxylat
MFCD00013531
p-Bromobenzoic acid,methyl ester
Benzoic acid, p-bromo-, methyl ester
Methyl 4-bromobenzoate
METHYL P-BROMOBENZOATE
methyl 4-bromo-benzoate
4-bromo-methylbenzoate
Benzoic acid,p-bromo-,methyl ester
Benzoic acid, p-bromo-, methyl ester (8CI)
Benzoic acid, 4-bromo-, methyl ester

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
262.2±13.0 °C at 760 mmHg

[ Melting Point ]:
77-81 °C(lit.)

[ Molecular Formula ]:
C₈H₇BrO₂

[ Molecular Weight ]:
215.044

[ Flash Point ]:
112.4±19.8 °C

[ Exact Mass ]:
213.962936

[ PSA ]:
26.30000

[ LogP ]:
2.95

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.550

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Synthesis of classical, three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine analogues as antifolates.

J. Med. Chem. 47(27) , 6893-6901, (2004)

Bridge homologation of the previously reported classical two-carbon-bridged antifolates, a 5-substituted 2,4-diaminofuro[2,3-d]pyrimidine (1) [which is a 6-regioisomer of LY231514 (Alimta)] and a 6-su...

Methyl 4-bromobenzoate. Bolte M and Wissler J.

Acta Crystallogr. Sect. E Struct. Rep. Online 62(3) , o1192-93, (2006)

Zeeman effect on the nuclear quadrupole resonance of 81Br in single crystals of methyl 4-bromobenzoate, 4, 4'-dibromodiphenyl-ether and 4, 4'-dibromodiphenylsulphide at 77 K. Ambrosetti R, et al.

Mol. Phys. 28(2) , 551-8, (1974)