4-Bromobenzyl alcohol

Names

[ CAS No. ]:
873-75-6

[ Name ]:
4-Bromobenzyl alcohol

[Synonym ]:
EINECS 212-851-7
MFCD00004650
p-Br benzyl alcohol
P-BROMOBENZYL ALCOHOL
4-bromobenzyl-alcohol
Brombenzylalcohol
4-Brom-benzyl alcohol
Benzyl alcohol,p-bromo
BroMo-benzyl alcohol
4-Bromobenzenemethanol
RARECHEM AL BD 0075
4-Br-Ph-CH2OH

Chemical & Physical Properties

[ Density]:
1.565 g/cm3

[ Boiling Point ]:
267.8ºC at 760 mmHg

[ Melting Point ]:
75-77 °C(lit.)

[ Molecular Formula ]:
C₇H₇BrO

[ Molecular Weight ]:
187.03400

[ Flash Point ]:
115.7ºC

[ Exact Mass ]:
185.96800

[ PSA ]:
20.23000

[ LogP ]:
1.94140

[ Index of Refraction ]:
1.591

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2906299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2906299090

[ Summary ]:
2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

One-pot synthesis of ferrocenyl ketones containing biaryls and 6-aryl-2-ferrocenylquinolines via Ir/Pd-cocatalyzed α-alkylation/Suzuki reaction.

J. Org. Chem. 78(17) , 8730-8, (2013)

An efficient PPh3-cyclometalated iridium(III) benzo[h]quinoline hydride 1/Pd(OAc)2-cocatalyzed three-component α-alkylation/Suzuki reaction has been developed. The three-component reaction of 4-bromob...

Proton NMR studies of the molecular basis for the anti-sickling activity of non-covalent antisickling compounds.

Prog. Clin. Biol. Res. 240 , 59-66, (1987)

Two new techniques of nuclear magnetic resonance spectroscopy are proposed to identify and characterize the binding sites of antisickling compounds to Hb S: measurements of the longitudinal relaxation...

Active site specific cadmium(II)-substituted horse liver alcohol dehydrogenase: crystal structures of the free enzyme, its binary complex with NADH, and the ternary complex with NADH and bound p-bromobenzyl alcohol.

Biochemistry 24(25) , 7503-10, (1985)

Three crystal structures have been determined of active site specific substituted Cd(II) horse liver alcohol dehydrogenase and its complexes. Intensities were collected for the free, orthorhombic enzy...