Methyl 4-boronobenzoate

Names

[ Name ]:
Methyl 4-boronobenzoate

[Synonym ]:
Benzoic acid, 4-borono-, methyl ester
[4-(Methoxycarbonyl)phenyl]boronic acid
MFCD01632203
Methyl 4-boronobenzoate
(4-methoxycarbonylphenyl)boronic acid

Biological Activity

[Description]:

4-Methoxycarbonylbenzeneboronic acid is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

[In Vitro]

它是一种试剂，用于串联型 Pd(II) 催化的氧化 Heck 反应和分子内 CH 酰胺化序列、铜介导的芳基硼酸与氟代烷基碘的无配体好氧氟代烷基化、芳基硼酸的一锅法硝化、铜-催化硝化和环缩合，然后是钯-膦催化的 Suzuki-Miyaura 偶联。用作 Reagent used in Reagent used in preparing biaryls via nickel-catalized Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, Chromones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting efficient hydrogen通过协同光激发和电子注入以及基于水杨酸盐的噻吩基苯甲酸作为大肠杆菌甲硫氨酸氨基肽酶抑制剂的进化。

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
345.8±44.0 °C at 760 mmHg

[ Melting Point ]:
197-200 °C(lit.)

[ Molecular Formula ]:
C₈H₉BO₄

[ Molecular Weight ]:
179.97

[ Flash Point ]:
162.9±28.4 °C

[ Exact Mass ]:
180.059387

[ PSA ]:
66.76000

[ LogP ]:
1.57

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.533

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

ipso-Nitration of arylboronic acids with bismuth nitrate and perdisulfate.

Org. Lett. 7th ed., 14 , 1736-1739, (2012)

An efficient and one pot synthetic method of ipso-nitration of arylboronic acids has been developed. The high efficiency, general applicability, and broader substrate scope including heterocycles and ...

Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.

Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012)

A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions--the oxidative Heck reaction an...

Pt nanoparticles@photoactive metal-organic frameworks: efficient hydrogen evolution via synergistic photoexcitation and electron injection.

J. Am. Chem. Soc. 17th ed., 134 , 7211-7214, (2012)

Pt nanoparticles of 2-3 nm and 5-6 nm in diameter were loaded into stable, porous, and phosphorescent metal-organic frameworks (MOFs 1 and 2) built from [Ir(ppy)(2)(bpy)](+)-derived dicarboxylate liga...