Thermolyses and reactions with nucleophiles of N-sulfur-group-substituted sulfoximines

S Oae, K Akutagawa, N Furukawa

Index: Oae, Shigeru; Akutagawa, Kunihiko; Furukawa, Naomichi Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 223 - 234

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Citation Number: 3

Abstract

Abstract Thermolyses and reactions with nucleophiles of S, S-diphenylsulfoximines (1) bearing the following N-sulfur-substituents, ie, Np-tolylthio-(b), Np-tolylsulfinyl-(c), N-(N′-p- tolylsulfonyl-p-toluenesulfinimidoyl)-(d), N-(S′, S′-diphenylsulfonio)-(e), Np-tolylsulfonyl- (f), and N-(N′-p-tolylsulfonyl-p-toluenesul-fonimidoyl)-(g), have been examined. The former three sulfoximines (1b-d) are thermally unstable and readily decompose to form diphenyl ...

 Related Synthetic Route
Phenyllithium Structure

591-51-5

Phenyllithium

Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

4-Methylphenyl phenyl sulfide Structure

3699-01-2

4-Methylphenyl ...

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Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

methyl iodide Structure

74-88-4

methyl iodide

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

1-Methyl-4-(methylsulfonyl)benzene Structure

3185-99-7

1-Methyl-4-(met...

Learn More
Sodium Methylate Structure

124-41-4

Sodium Methylate

Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Methyl 4-methylbenzenesulfinate Structure

672-78-6

Methyl 4-methyl...

Learn More
Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~0%

Bis(4-methylphenyl) sulfide Structure

620-94-0

Bis(4-methylphe...

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More
Piperidine Structure

110-89-4

Piperidine

Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

~0%

N/A Structure

18511-53-0

N/A

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More
Piperidine Structure

110-89-4

Piperidine

Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

~0%

1-(toluene-4-sulfinyl)piperidine Structure

6873-93-4

1-(toluene-4-su...

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More
Sodium toluene-4-sulphinate Structure

824-79-3

Sodium toluene-...

Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

4-Methylbenzenesulfonothioic acid S-(4-methylphenyl) ester Structure

2943-42-2

4-Methylbenzene...

Learn More
Phenyllithium Structure

591-51-5

Phenyllithium

Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

2-methyldibenzo[b,d]thiophene 5-oxide Structure

77096-69-6

2-methyldibenzo...

Learn More
Diethylamine Structure

109-89-7

Diethylamine

Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

N,N-diethyl-4-methylbenzenesulfinamide Structure

6873-59-2

N,N-diethyl-4-m...

Learn More
Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

N-Methylaniline Structure

100-61-8

N-Methylaniline

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

N,4-dimethyl-N-phenylbenzenesulfinamide Structure

33692-24-9

N,4-dimethyl-N-...

Learn More
Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

p-Tolyl sulfoxide (8CI) Structure

1774-35-2

p-Tolyl sulfoxi...

Learn More
METHYLMAGNESIUM BROMIDE Structure

75-16-1

METHYLMAGNESIUM...

Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

~0%

methyl p-tolyl sulfoxide Structure

934-72-5

methyl p-tolyl ...

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More
Phenyllithium Structure

591-51-5

Phenyllithium

N-(N'-p-tolylsulfonyl)-p-toluenesulfinimidoylsulfoximine Structure

91378-38-0

N-(N'-p-tolylsu...

~0%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

S-(p-tolyl)-S-phenyl-N-(p-tolylsulfonyl)sulfilimine Structure

24702-37-2

S-(p-tolyl)-S-p...

Learn More
Sodium 4-methylbenzenethiolate Structure

10486-08-5

Sodium 4-methyl...

Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

~0%

para-Tolyl disulfide Structure

103-19-5

para-Tolyl disulfide

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More
Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

~%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

P-toluenethiol Structure

106-45-6

P-toluenethiol

Learn More
METHYLMAGNESIUM BROMIDE Structure

75-16-1

METHYLMAGNESIUM...

Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

~60%

methyl p-tolyl sulfoxide Structure

934-72-5

methyl p-tolyl ...

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More
Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

N-Methylaniline Structure

100-61-8

N-Methylaniline

~75%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

N,4-dimethyl-N-phenylbenzenesulfinamide Structure

33692-24-9

N,4-dimethyl-N-...

Learn More
Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

methyl iodide Structure

74-88-4

methyl iodide

~79%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

1-Methyl-4-(methylsulfonyl)benzene Structure

3185-99-7

1-Methyl-4-(met...

Learn More
Benzenesulfinamide, 4-methyl-N-(oxidodiphenyl-λ4-sulfanylidene) Structure

91378-37-9

Benzenesulfinam...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~71%

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

p-Tolyl sulfoxide (8CI) Structure

1774-35-2

p-Tolyl sulfoxi...

Learn More
Sulfoximine, N-[(4-methylphenyl)thio]-S,S-diphenyl Structure

91378-34-6

Sulfoximine, N-...

P-TOLYLMAGNESIUM BROMIDE Structure

4294-57-9

P-TOLYLMAGNESIU...

~98%

Bis(4-methylphenyl) sulfide Structure

620-94-0

Bis(4-methylphe...

Sulfoximine,S,S-diphenyl Structure

22731-83-5

Sulfoximine,S,S...

Learn More

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