Synthesis, Structure, and Thermolysis Mechanism of S-Alkoxythiazynes.

T Yoshimura, M Ohkubo, T Fujii, H Kita…

Index: Yoshimura, Toshiaki; Ohkubo, Masanori; Fujii, Takayoshi; Kita, Hiroshi; Wakai, Youko; Ono, Shin; Morita, Hiroyuki; Shimasaki, Choichiro; Horn, Ernst Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 7 p. 1629 - 1637

Full Text: HTML

Citation Number: 17

Abstract

S-Alkoxy-S, S-diarylthiazynes were prepared by two methods: the alkaline hydrolysis of S, S- diaryl-N-halosulfilimines in aqueous alcohols and the reaction of S, S-diaryl-S- fluorothiazynes with sodium alkoxides. The structure of S, S-diphenyl-S-propoxythiazyne was determined by an X-ray crystallographic analysis, which showed a short SN bond length of 1.441 (3) Å. The thermolysis of S-alkoxythiazynes gave elimination products, ...

 Related Synthetic Route
N/A Structure

127022-75-7

N/A

~98%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-Diphenyl-N.bromosulfilimine Structure

42787-34-8

S,S-Diphenyl-N....

~18%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Methanol Structure

67-56-1

Methanol

S,S-Diphenyl-N.bromosulfilimine Structure

42787-34-8

S,S-Diphenyl-N....

~78%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

N/A Structure

127022-75-7

N/A

Methanol Structure

67-56-1

Methanol

S,S-Diphenyl-N-chlorosulfilimine Structure

42787-33-7

S,S-Diphenyl-N-...

~51%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

N/A Structure

127022-75-7

N/A

1-Propanol Structure

71-23-8

1-Propanol

S,S-Diphenyl-N-chlorosulfilimine Structure

42787-33-7

S,S-Diphenyl-N-...

~61%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Detail
Ethanol Structure

64-17-5

Ethanol

S,S-Diphenyl-N.bromosulfilimine Structure

42787-34-8

S,S-Diphenyl-N....

~22%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Detail
N/A Structure

127022-75-7

N/A

~36%

Diphenylsulfid Structure

139-66-2

Diphenylsulfid

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

S,S-Diphenyl-N-iodosulfilimine Structure

42787-35-9

S,S-Diphenyl-N-...

~89%

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

S,S-Diphenyl-N.bromosulfilimine Structure

42787-34-8

S,S-Diphenyl-N....

~73%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

1-Propanol Structure

71-23-8

1-Propanol

S,S-Diphenyl-N-chlorosulfilimine Structure

42787-33-7

S,S-Diphenyl-N-...

~0%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Detail
Ethanol Structure

64-17-5

Ethanol

S,S-Diphenyl-N.bromosulfilimine Structure

42787-34-8

S,S-Diphenyl-N....

~43%

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Detail
propyloxy(diphenyl)-λ6-sulfanenitrile Structure

143885-02-3

propyloxy(diphe...

~73%

Diphenylsulfid Structure

139-66-2

Diphenylsulfid

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

S,S-Diphenyl-N.bromosulfilimine Structure

42787-34-8

S,S-Diphenyl-N....

~%

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

S,S-Diphenyl-N-chlorosulfilimine Structure

42787-33-7

S,S-Diphenyl-N-...

~%

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

N/A Structure

127022-75-7

N/A

~21%

Diphenylsulfid Structure

139-66-2

Diphenylsulfid

Sulfoximine,S,S-diphenyl- Structure

22731-83-5

Sulfoximine,S,S...

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

fluoro(diphenyl)-λ6-sulfanenitrile Structure

67248-39-9

fluoro(diphenyl...

~%

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

N/A Structure

127022-75-7

N/A

~%

Formaldehyde Structure

50-00-0

Formaldehyde

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

isopropyloxy(diphenyl)-λ6-sulfanenitrile Structure

143885-03-4

isopropyloxy(di...

~%

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Acetone Structure

67-64-1

Acetone

propyloxy(diphenyl)-λ6-sulfanenitrile Structure

143885-02-3

propyloxy(diphe...

~%

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...

Propionaldehyde Structure

123-38-6

Propionaldehyde

S,S-diphenyl-S-[1,1-2H2]propoxythiazyne Structure

212077-68-4

S,S-diphenyl-S-...

~%

propanal-d1 Structure

5972-03-2

propanal-d1

S,S-DIPHENYLSULFILIMINE Structure

36744-90-8

S,S-DIPHENYLSUL...


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