triphenyl(trimethylsilylimino)-λ5-phosphane

triphenyl(trimethylsilylimino)-λ5-phosphane Structure
triphenyl(trimethylsilylimino)-λ5-phosphane structure
Common Name triphenyl(trimethylsilylimino)-λ5-phosphane
CAS Number 13892-06-3 Molecular Weight 349.48100
Density 1g/cm3 Boiling Point 428.9ºC at 760 mmHg
Molecular Formula C21H24NPSi Melting Point 76-82ºC(lit.)
MSDS USA Flash Point 213.2ºC

Pyridine-phosphinimine ligand-accelerated Cu(I)-catalyzed azide-alkyne cycloaddition for preparation of 1-(pyridin-2-yl)-1,2,3-triazole derivatives.

Org. Biomol. Chem. 12(31) , 5954-63, (2014)

A series of phosphinimine ligands were designed and used in the Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction of tetrazolo[1,5-a]pyridines and alkynes for the first time. By optimizing the reaction conditions, an efficient catalytic system (CuCl...