1,1-Bis(diphenylphosphino)ferrocene

1,1-Bis(diphenylphosphino)ferrocene Structure
1,1-Bis(diphenylphosphino)ferrocene structure
Common Name 1,1-Bis(diphenylphosphino)ferrocene
CAS Number 12150-46-8 Molecular Weight 558.410
Density N/A Boiling Point 363.8ºC at 760mmHg
Molecular Formula C34H28FeP2 Melting Point 181-182 °C (dec.)(lit.)
MSDS USA Flash Point 182.8ºC

Catalytic selective deuteration of halo(hetero)arenes.

Org. Biomol. Chem. 14 , 3091-7, (2016)

Deuterium labeled aromatic and heteroaromatic compounds are synthesized in good to excellent yields with >98% deuterium purity via palladium catalyzed deuterodehalogenation reaction using commercially available and inexpensive reagents. Selective deuteration ...

A new one-Pot synthesis of alkynylphosphonates

Org. Lett. 2 , 3873, (2000)

A method for the palladium-catalyzed synthesis of alkynylphosphonates from 1,1-dibromo-1-alkenes has been developed. In general, the best catalyst system for this transformation was found to be Pd(OAc)(2), dppf, H-phosphonate, propylene oxide, DMF, 80 degrees...

Stereoselective ring opening of meso bicyclic hydrazines: a straightforward approach to hydrazino cyclopentenic cores.

Org. Lett. 5 , 4771, (2003)

The diastereoselective synthesis of hydrazinocyclopentenes 6 or 7 can be achieved in a straightforward manner from Diels-Alder adduct 4 using an acid-catalyzed rearrangement or a palladium-catalyzed allylic substitution reaction. In the latter case, enantioen...

Zirconium ion selective electrode based on bis(diphenylphosphino) ferrocene incorporated in a poly(vinyl chloride) matrix.

Anal. Chim. Acta 584(2) , 302-307, (2007)

A novel potentiometric zirconium--PVC matrix membrane sensor incorporating bis(diphenylphosphino) ferrocene as an electroactive material and tris(2-ethylhexyl)phosphate as solvent mediator is described. In mixed acetate buffer solution of pH 4.8, the sensor d...

Tetrahedron 62 , 9002, (2006)

Tanimori, Shinji; et al.

Synthesis 5 , 865-869, (2006)

Palucki, M.;Wolfe, J. P.; Buchwald, S.-L.

J. Am. Chem. Soc. 118 , 10333, (1996)

Driver, M. S.; Hartwig, J. F.

J. Am. Chem. Soc. 118 , 7217, (1996)

Wolfe, J. P.; Buchwald, S. L.

J. Am. Chem. Soc. 119 , 6054, (1997)

Anastasia, L.; Dumond, Y. R.; Negishi, E.

European J. Org. Chem. , 3039, (2001)