2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE
2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE structure
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Common Name | 2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE | ||
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| CAS Number | 95452-06-5 | Molecular Weight | 234.49700 | |
| Density | 1.01 g/mL at 25ºC(lit.) | Boiling Point | 124ºC5 mm Hg(lit.) | |
| Molecular Formula | C10H22S2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 221 °F | |
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Multicomponent linchpin couplings of silyl dithianes: synthesis of the Schreiber C(16-28) trisacetonide subtarget for mycoticins A and B.
Org. Lett. 1(12) , 2001-4, (1999) [formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-component linchpin coupling tactic. |
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A general, convergent strategy for the construction of indolizidine alkaloids: total syntheses of (-)-indolizidine 223AB and alkaloid (-)-205B.
J. Org. Chem. 71 , 2547, (2006) N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of protected 1,5-amino alcohols. This tactic, in conjunction with ... |
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Total synthesis of the neotropical poison-frog alkaloid (-)-205B.
Org. Lett. 7 , 3247, (2005) [reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot sequential construction of the embedded indolizidine ring, and r... |