(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Structure
(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine structure
Common Name (11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS Number 490023-37-5 Molecular Weight 435.453
Density N/A Boiling Point 635.4±48.0 °C at 760 mmHg
Molecular Formula C28H22NO2P Melting Point 155-159ºC
MSDS Chinese USA Flash Point 338.1±29.6 °C

Highly enantioselective rhodium-catalyzed hydrogenation of beta-dehydroamino acid derivatives using monodentate phosphoramidites.

J. Am. Chem. Soc. 124 , 14552, (2002)

New and very easily accessible monodentate phosphoramidite ligands have been developed that lead to excellent ee's and full conversions in the hydrogenation of (E)- and (Z)-beta-dehydroamino acid derivatives with both aliphatic and aromatic side chains. Parti...

J. Organomet. Chem. 692 , 428, (2007)