Tri-tert-butylphosphine tetrafluoroborate

Tri-tert-butylphosphine tetrafluoroborate Structure
Tri-tert-butylphosphine tetrafluoroborate structure
Common Name Tri-tert-butylphosphine tetrafluoroborate
CAS Number 131274-22-1 Molecular Weight 290.13
Density N/A Boiling Point N/A
Molecular Formula C12H27P.BF4.H Melting Point 261 °C(lit.)
MSDS Chinese USA Flash Point N/A

Heck coupling with nonactivated alkenyl tosylates and phosphates: examples of effective 1,2-migrations of the alkenyl palladium(II) intermediates.

Angew. Chem. Int. Ed. Engl. 45 , 3349, (2006)

Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine.

Tetrahedron Asymmetry 6 , 1283, (1995)

This communication discloses the first instance of the enantioselective Pd-catalyzed alpha-arylation of N-Boc-pyrrolidine. The methodology relies on Beak's sparteine-mediated, enantioselective deprotonation of N-Boc-pyrrolidine to form the 2-pyrrolidinolithiu...

Synlett , 3001, (2006)