Bis[rhodium(a,a,a#,a#-tetramethyl-1,3-benzenedipropionic acid)]

Bis[rhodium(a,a,a#,a#-tetramethyl-1,3-benzenedipropionic acid)] Structure
Bis[rhodium(a,a,a#,a#-tetramethyl-1,3-benzenedipropionic acid)] structure
Common Name Bis[rhodium(a,a,a#,a#-tetramethyl-1,3-benzenedipropionic acid)]
CAS Number 819050-89-0 Molecular Weight 762.49800
Density N/A Boiling Point 437ºC at 760 mmHg
Molecular Formula C32H44O8Rh2 Melting Point >300ºC
MSDS Chinese USA Flash Point 232.2ºC

Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights.

J. Am. Chem. Soc. 129 , 562, (2007)

Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiome...