(4-Boc-aminophenyl)boronic acid

(4-Boc-aminophenyl)boronic acid Structure
(4-Boc-aminophenyl)boronic acid structure
Common Name (4-Boc-aminophenyl)boronic acid
CAS Number 380430-49-9 Molecular Weight 237.06
Density 1.2±0.1 g/cm3 Boiling Point N/A
Molecular Formula C11H16BNO4 Melting Point 199-204 °C (dec.)(lit.)
MSDS Chinese USA Flash Point N/A

Rhodium-catalyzed asymmetric allylic substitution with boronic acid nucleophiles.

Org. Lett. 8 , 4569, (2006)

An enantio-, regio-, and diastereoselective rhodium(I)-catalyzed desymmetrization of a meso-cyclic allylic dicarbonate with organoboronic acid nucleophiles is described. The rhodium(I) catalyst formed in situ from [Rh(cod)OH]2 and Xyl-P-PHOS allowed the S(N)2...