trans-4-(2-Thienyl)-3-buten-2-one
trans-4-(2-Thienyl)-3-buten-2-one structure
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Common Name | trans-4-(2-Thienyl)-3-buten-2-one | ||
|---|---|---|---|---|
| CAS Number | 33603-63-3 | Molecular Weight | 152.21400 | |
| Density | 1.151 g/mL at 25ºC(lit.) | Boiling Point | 271.5ºC at 760 mmHg | |
| Molecular Formula | C8H8OS | Melting Point | 25-26ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 230 °F | |
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Indium-mediated beta-allylation, beta-propargylation, and beta-allenylation onto alpha,beta-unsaturated ketones: reactions of in-situ-generated 3-tert-butyldimethylsilyloxyalk-2-enylsulfonium salts with in-situ-generated organoindium reagents.
J. Am. Chem. Soc. 125(32) , 9682-8, (2003) 3-tert-Butyldimethylsilyloxyalk-2-enylsulfonium salts, generated in situ from the reaction of alpha,beta-enones with dimethyl sulfide in the presence of TBSOTf, underwent a novel nucleophilic substitution with allylindiums to give silyl enol ethers of delta,e... |
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