2,4-dithiouracil
2,4-dithiouracil structure
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Common Name | 2,4-dithiouracil | ||
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| CAS Number | 2001-93-6 | Molecular Weight | 144.218 | |
| Density | 1.5±0.1 g/cm3 | Boiling Point | 225.6±23.0 °C at 760 mmHg | |
| Molecular Formula | C4H4N2S2 | Melting Point | 279-281 °C (dec.)(lit.) | |
| MSDS | Chinese USA | Flash Point | 90.3±22.6 °C | |
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Photoelectron spectroscopic study of the negative ions of 4-thiouracil and 2,4-dithiouracil.
J. Chem. Phys. 134(7) , 074304, (2011) We report the photoelectron spectra of the negative ions of 4-thiouracil (4-TU)(-) and 2,4-dithiouracil (2,4-DTU)(-). Both of these spectra are indicative of valence anions, and they are each dominated by a single broad band with vertical detachment energies ... |
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Electron propagator and coupled-cluster calculations on the photoelectron spectra of thiouracil and dithiouracil anions.
J. Chem. Phys. 134(7) , 074305, (2011) Electron affinities, vertical electron detachment energies, and isomerization energies of 4-thiouracil, 2-thiouracil, and 2,4-dithiouracil and their valence anions have been calculated with ab initio electron propagator and other many-body methods. Anions in ... |
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Photochemistry and electrochemistry of anticancer uracils.
J. Photochem. Photobiol. B, Biol. 117 , 269-77, (2012) The redox mechanism and electronic absorption behavior of a commercial anticancer drug, 5-fluorouracil (5-FU) and two potential anticancer drugs, 2-thiouracil (2-TU) and dithiouracil (DTU) have been investigated in a wide pH range by UV-Vis spectroscopy, cycl... |
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Application of 2-thiouracil and 2,4-dithiouracil for the determination of metal ions. Part I. Spectrophotometric determination of copper and silver.
Ann. Univ. Mariae Curie. Sklodowska. Med. 38 , 135-41, (1983)
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Gas-phase reactivity of uracil, 2-thiouracil, 4-thiouracil, and 2,4-dithiouracil towards the Cu+ cation: a DFT study.
ChemPhysChem 4(9) , 1011-6, (2003)
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Spectroscopic identification of 2,4-pyrimidinedithiol; an experimental matrix isolation and ab initio Hartree-Fock and density functional theory study.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 54A(5) , 685-93, (1998) 2,4-Pyrimidinedithiol (the dithiol form of 2,4-dithiouracil) was generated by UV (lambda > 335 nm) irradiation of the dithione form of 2,4-dithiouracil isolated in low-temperature argon or nitrogen matrices. The IR and UV spectra of the photoproduct are repor... |
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2,4-dithiouracil: the reproducible H-bonded structural motifs in the complexes with 18-membered crown ethers.
Org. Biomol. Chem. 3(16) , 3054-8, (2005) 2,4-dithiouracil (DTU) forms in the crystals the H-bonded monohydrates of a 1:1:1 ratio with 18-crown-6 (18C6) 1, cis,syn,cis-isomer of dicyclohexano-18-crown-6 (DCH6A) 2, and benzo-18-crown-6 (B18C6) 3, while the anhydrous adduct with cis,anti,cis-isomer of ... |