(3-Bromophenyl)boronic acid

(3-Bromophenyl)boronic acid Structure
(3-Bromophenyl)boronic acid structure
Common Name (3-Bromophenyl)boronic acid
CAS Number 89598-96-9 Molecular Weight 200.83
Density 1.7±0.1 g/cm3 Boiling Point 330.5±44.0 °C at 760 mmHg
Molecular Formula C6H6BBrO2 Melting Point 164-168 °C(lit.)
MSDS Chinese USA Flash Point 153.7±28.4 °C

ipso-nitration of arylboronic acids with chlorotrimethylsilane-nitrate salts.

Org. Lett. 6 , 2205-2207, (2004)

[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the corresponding nitroarenes in moderate to excellent yields. High sele...