1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate structure
|
Common Name | 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate | ||
|---|---|---|---|---|
| CAS Number | 35193-63-6 | Molecular Weight | 348.289 | |
| Density | 1.5±0.1 g/cm3 | Boiling Point | 619.5±38.0 °C at 760 mmHg | |
| Molecular Formula | C20H13O4P | Melting Point | 310ºC | |
| MSDS | Chinese USA | Flash Point | 328.5±26.8 °C | |
|
Multivariate approach for the enantioselective analysis in micellar electrokinetic chromatography-mass spectrometry:I. Simultaneous optimization of binaphthyl derivatives in negative ion mode
J. Chromatogr. A. 1216(5) , 845-56, (2009) A mixture of two molecular micelles polysodium N-undecenoxy carbonyl- l-leucinate, (poly- l-SUCL) and polysodium N-undecanoyl leucylvalinate, (poly- l-SULV) was utilized in micellar electrokinetic chromatography-electrospray ionization-mass spectrometry (MEKC... |
|
|
Comparison of alkylglycoside surfactants in enantioseparation by capillary electrophoresis.
Electrophoresis 18(6) , 912-918, (1997) Three alkylglycoside surfactants, namely n-octyl-beta-D-glucopyranoside (OG), n-nonyl-beta-D-glucopyranoside (NG), and n-octyl-beta-D-maltopyranoside (OM), were compared in the enantiomeric separation of dansyl amino acids, binaphthyl phosphate, bupivacaine a... |
|
|
Optimization of 12 chiral analytes with 8 polymeric surfactants.
J. Chromatogr. Sci. 46(9) , 757-63, (2008) This manuscript discusses the results of studies that were performed to determine optimum capillary electrophoresis (CE) conditions for the enantiomeric resolution of twelve chiral analytes with eight amino acid based polymeric surfactants. The parameters tha... |
|
|
Use of multivariate analysis for optimization of separation parameters and prediction of migration time, resolution, and resolution per unit time in micellar electrokinetic chromatography.
Electrophoresis 27(21) , 4127-40, (2006) The optimization of separation parameters in chromatography for better separation and resolution of analytes continues to be a labor intensive procedure usually performed by a trial and error method. A multivariate analysis in the form of multilinear regressi... |
|
|
Chiral selectivity of guanosine media in capillary electrophoresis.
Electrophoresis 32(13) , 1735-41, (2011) Gels formed by self-association of monomeric guanosine compounds join numerous other agents such as cyclodextrins, crown ethers, chiral surfactants, antibiotics, proteins, and polysaccharides for chiral separations. Guanosine gels (G-gels) are self-assembled ... |
|
|
Enantioseparation using selected polysaccharides as chiral buffer additives in capillary electrophoresis.
J. Chromatogr. A. 773(1-2) , 331-8, (1997) Selected water-soluble, native polysaccharides--such as amylose, laminaran, pullulan--and derivatized polysaccharides--methyl cellulose, hydroxypropyl cellulose, and carboxymethyl amylose sodium salt (CM-Am)--were investigated as chiral selectors in capillary... |
|
|
Facile and efficient enantioselective Strecker reaction of ketimines by chiral sodium phosphate.
Chemistry 15(24) , 6008-14, (2009) A facile and efficient enantioselective Strecker reaction of ketimines catalyzed by a chiral alkali-metal salt has been developed. When 10 mol % BNPNa (BNP = 1,1'-binaphthyl-2,2'-diylphosphate) prepared in situ and 10 mol % para-tert-butyl-ortho-adamantylphen... |
|
|
Comparative study on the enantiomer separation of 1,1'-binaphthyl-2,2'diyl hydrogenphosphate and 1,1'-bi-2-naphthol by liquid chromatography and capillary electrophoresis using single and combined chiral selector systems.
J. Chromatogr. A. 977(2) , 225-37, (2002) The chiral recognition ability of single and dual selectors, that were used as additives, have been investigated by HPLC and CE. Native beta- and gamma-cyclodextrins, permethylated beta-cyclodextrin, hydroxypropyl-beta-cyclodextrin, cholic acid and taurodeoxy... |
|
|
Fluorescence anisotropy as a measure of chiral recognition.
J. Am. Chem. Soc. 123(13) , 3173-4, (2001)
|
|
|
Enantioseparation of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis.
Chirality 10(1-2) , 134-9, (1998) Twelve different disaccharides and a series of noncyclic malto- and cello-oligosaccharides were used as chiral selectors in capillary electrophoresis (CE). Most saccharides resolved the enantiomers of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate... |