Naphtho[1,2-b]thianaphthene

Naphtho[1,2-b]thianaphthene Structure
Naphtho[1,2-b]thianaphthene structure
Common Name Naphtho[1,2-b]thianaphthene
CAS Number 239-35-0 Molecular Weight 234.316
Density 1.3±0.1 g/cm3 Boiling Point 434.3±14.0 °C at 760 mmHg
Molecular Formula C16H10S Melting Point 188-190ºC(lit.)
MSDS Chinese USA Flash Point 163.0±6.3 °C

Electrophilic oxidant produced in the photodeoxygenation of 1,2-benzodiphenylene sulfoxide.

J. Org. Chem. 66(13) , 4576-9, (2001)

We report that the photodeoxygenation of 1,2-benzodiphenylene sulfoxide, 1, generates an intermediate capable of oxidizing the solvent benzene to phenol. The reactivity of the intermediate was probed with various substrates (2-methylbutane, chloride ion, and ...

Gauging the significance of atomic oxygen [O(3P)] in sulfoxide photochemistry. A method for hydrocarbon oxidation.

J. Org. Chem. 68(5) , 1886-91, (2003)

A liquid-phase photolysis of 1,2-benzodiphenylene sulfoxide, 1, and dibenzothiophene sulfoxide, 2, was used to generate atomic oxygen [O(3P)] or an equivalent active oxygen species. The reaction for sulfoxide photodeoxygenation was similar to a microwave disc...

Direct automatic screening and individual determination of polycyclic aromatic hydrocarbons using supercritical fluid extraction coupled on-line with liquid chromatography and fluorimetric detection. Zougagh M, et al.

Anal. Chim. Acta 524(1) , 279-85, (2004)