Ethyl Methylsulfonylacetate

Ethyl Methylsulfonylacetate Structure
Ethyl Methylsulfonylacetate structure
Common Name Ethyl Methylsulfonylacetate
CAS Number 4455-15-6 Molecular Weight 166.19500
Density 1.234 g/mL at 25 °C(lit.) Boiling Point 111-113 °C0.2 mm Hg(lit.)
Molecular Formula C5H10O4S Melting Point N/A
MSDS Chinese Flash Point >230 °F

Knoevenagel reaction in [MMIm][MSO₄]: synthesis of coumarins.

Molecules 16(6) , 4379-88, (2011)

The ionic liquid 1,3-dimethylimidazolium methyl sulfate, [MMIm][MSO₄], together with a small amount of water (the amount taken up by the ionic liquid upon exposure to air), acts efficiently as both solvent and catalyst of the Knoevenagel condensation reaction...

Yonemitsu-type condensations catalysed by proline and Eu (OTf) 3. Renzetti A, et al.

RSC Advances 4(89) , 47992-47999, (2014)

Rhodium (II)-mediated reactions of thiobenzoylketene S, N-acetals with a-diazo carbonyl compounds: synthesis of 2-substituted 3-alkylamino-5-phenylthiophenes. Song HM and Kim K.

J. Chem. Soc. Perkin Trans. I 21 , 2414-2417, (2002)