(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
![(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Structure](https://image.chemsrc.com/caspic/019/497883-22-4.png)
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine structure
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Common Name | (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | ||
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| CAS Number | 497883-22-4 | Molecular Weight | 539.603 | |
| Density | N/A | Boiling Point | 710.7±63.0 °C at 760 mmHg | |
| Molecular Formula | C36H30NO2P | Melting Point | 102-103°C | |
| MSDS | N/A | Flash Point | 383.6±33.7 °C | |
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Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications.
Org. Lett. 4 , 3835, (2002) [formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, as silyl enol ethers with TMSOTf in apolar solvents or with... |
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Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to (2-pyridyl)sulfonyl imines of chalcones.
J. Org. Chem. 70 , 7451, (2005) [reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reagents to (2-pyridylsulfonyl)imines of chalcones. This process... |
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Synlett , 1375, (2001)
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Org. Biomol. Chem. 4 , 1278, (2006)
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