tBu3PPdG2 catalyst

tBu3PPdG2 catalyst Structure
tBu3PPdG2 catalyst structure
Common Name tBu3PPdG2 catalyst
CAS Number 1375325-71-5 Molecular Weight 512.404
Density N/A Boiling Point N/A
Molecular Formula C24H37ClNPPd Melting Point 159 °C(dec.)
MSDS USA Flash Point N/A

The development of versatile methods for palladium-catalyzed coupling reactions of aryl electrophiles through the use of P(t-Bu)3 and PCy3 as ligands.

Acc. Chem. Res. 41(11) , 1555-64, (2008)

Metal-catalyzed coupling reactions of aryl electrophiles with organometallics and with olefins serve as unusually effective tools for forming new carbon-carbon bonds. By 1998, researchers had developed catalysts that achieved reactions of aryl iodides, bromid...

Pd/P(t-Bu)(3): a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides.

J. Am. Chem. Soc. 124 , 6343, (2003)

Pd/P(t-Bu)(3) serves as an unusually reactive catalyst for Stille reactions of aryl chlorides and bromides, providing solutions to a number of long-standing challenges. An unprecedented array of aryl chlorides can be cross-coupled with a range of organotin re...