[(S,S)-Teth-TsDpen RuCl]

[(S,S)-Teth-TsDpen RuCl] Structure
[(S,S)-Teth-TsDpen RuCl] structure
Common Name [(S,S)-Teth-TsDpen RuCl]
CAS Number 851051-43-9 Molecular Weight 614.12000
Density N/A Boiling Point N/A
Molecular Formula C30H25ClN2O2RuS Melting Point 260-268°C
MSDS USA Flash Point N/A

A class of ruthenium(II) catalyst for asymmetric transfer hydrogenations of ketones.

J. Am. Chem. Soc. 127 , 7318-7319, (2005)

Ruthenium dimer 6 (readily available in two steps from TsDPEN) is converted directly to monomeric asymmetric transfer hydrogenation catalyst 3 in situ under the conditions employed for ketone reduction. Catalyst 3 is a significantly more active catalyst for t...