D-Plenylglycinol
D-Plenylglycinol structure
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Common Name | D-Plenylglycinol | ||
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| CAS Number | 56613-80-0 | Molecular Weight | 137.18 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 261.0±0.0 °C at 760 mmHg | |
| Molecular Formula | C8H11NO | Melting Point | 76-79 °C | |
| MSDS | Chinese USA | Flash Point | 125.3±21.8 °C | |
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Straightforward synthesis of (S)- and (R)-alpha-trifluoromethyl proline from chiral oxazolidines derived from ethyl trifluoropyruvate.
Org. Lett. 8 , 6123, (2006) [Structure: see text] A concise synthesis of both enantiomers of alpha-Tfm-proline and (S)-alpha-Tfm-prolinol from ethyl trifluoropyruvate is reported. The key step is a diastereoselective allylation reaction of ethyl trifluoropyruvate and (R)-phenylglycinol-... |
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Amedjkouh, M.; Westerlund, K.
Tetrahedron Lett. 45 , 5175, (2004)
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Tetrahedron Lett. 45 , 5287, (2004)
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