| 中文名 | 异丁酸三甲基硅酯 |
|---|---|
| 英文名 | trimethylsilyl 2-methylpropanoate |
| 中文别名 | 三甲基甲硅烷基 异丁酸 |
| 英文别名 |
Isobuttersaeure-trimethylsilylester
isobutyric acid trimethylsilanyl ester Propanoic acid, 2-methyl-, trimethylsilyl ester 2-methylpropionic acid trimethylsilylester Trimethylsilyl isobutyrate trimethylsilyl 2-methylpropionate Isobutyryloxy-trimethyl-silan Isobutyric acid, trimethylsilyl ester Isobutyric acid,trimethylsilyl ester MFCD01632553 Trimethyl-isobutyryloxy-silan Trimethylsilyl 2-methylpropanoate |
| 密度 | 0.9±0.1 g/cm3 |
|---|---|
| 沸点 | 134.2±9.0 °C at 760 mmHg |
| 分子式 | C7H16O2Si |
| 分子量 | 160.286 |
| 闪点 | 29.2±14.3 °C |
| 精确质量 | 160.091949 |
| PSA | 26.30000 |
| LogP | 2.11 |
| 外观性状 | 透明无色液体 |
| 蒸汽压 | 8.2±0.2 mmHg at 25°C |
| 折射率 | 1.404 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：132 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 计算化学数据 纠错 | 编辑1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:3 5.互变异构体数量:无 6.拓扑分子极性表面积26.3 7.重原子数量:10 8.表面电荷:0 9.复杂度:124 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 16883-61-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 132 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: Molecular Weight: 160.29 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 16883-61-7 unlisted. LD50/LC50: Not available. Carcinogenicity: TRIMETHYLSILYL ISOBUTYRATE - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 16883-61-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 16883-61-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 16883-61-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 安全声明 (欧洲) | S24/25 |
|---|---|
| 海关编码 | 2931900090 |
|
~20%
16883-61-7 |
| 文献：Journal of Organic Chemistry, , vol. 47, # 15 p. 2900 - 2903 |
|
~%
16883-61-7 |
| 文献：Journal of Organometallic Chemistry, , vol. 46, p. 73 - 87 |
|
~%
16883-61-7 |
| 文献：Central European Journal of Chemistry, , vol. 9, # 5 p. 813 - 824 |
|
~%
16883-61-7 |
| 文献：Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 528 Chem.Abstr., , # 6298 |
|
~%
16883-61-7 |
| 文献：J. Gen. Chem. USSR (Engl. Transl.), , vol. 50, # 5 p. 1059 - 1064,851 - 855 |
| 海关编码 | 2931900090 |
|---|---|
| 中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
