中文名 | N,O-双(三甲基硅烷基)三氟乙酰胺 |
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英文名 | N,O-bis(trimethylsilyl)trifluoroacetamide |
中文别名 |
BSTFA,衍生化级
N,O-双(三甲基硅基)三氟乙酰胺 双(三甲基硅基)三氟乙酰胺 |
英文别名 |
bis(trimethylsilyl)trifluoroacetamide
N,O-bis-TMS-trifluoroacetamide N,O-Bis(trimethylsilyl)trifluoroacetamide Kit BSTFA 1 mL × Bis(trimethylsilyl) 8 Reaction vial,capacity N,O-BSTFA EINECS 247-103-9 Acetamide, 2,2,2-trifluoro-N,N-bis(trimethylsilyl)- REGISIL(R) RC-1 N,N-bis(trimethylsilyl)-2,2,2-trifluoroacetamide bstfa kit BSTFA REGISIL RC-3 REGISIL RC-2 REGISIL RC-1 bstfa + tmcs 2,2,2-Trifluoro-N,N-bis(trimethylsilyl)acetamide MFCD00008269 |
密度 | 1.0±0.1 g/cm3 |
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沸点 | 170.0±50.0 °C at 760 mmHg |
熔点 | -10°C |
分子式 | C8H18F3NOSi2 |
分子量 | 257.401 |
闪点 | 56.6±30.1 °C |
精确质量 | 257.087891 |
PSA | 21.59000 |
LogP | 3.42 |
外观性状 | 透明至淡黄色透明液体 |
蒸汽压 | 1.5±0.3 mmHg at 25°C |
折射率 | 1.396 |
储存条件 | 2-8℃ |
稳定性 | 如果遵照规格使用和储存则不会分解 避免接触氧化物,酸 |
水溶解性 | hydrolyses |
分子结构 | 1、 摩尔折射率:60.75 2、 摩尔体积(cm3/mol):252.8 3、 等张比容(90.2K):523.1 4、 表面张力(dyne/cm):18.3 5、 极化率(10-24cm3):24.08 |
计算化学 | 1、 氢键供体数量:0 2、 氢键受体数量:5 3、 可旋转化学键数量:3 4、 拓扑分子极性表面积(TPSA):21.6 5、 重原子数:15 6、 表面电荷:0 7、 复杂度:250 8、 同位素原子数量:0 9、 确定原子立构中心数量:0 10、 不确定原子立构中心数量:0 11、 确定化学键立构中心数量:0 12、 不确定化学键立构中心数量:1 13、 共价键单元数量:1 |
更多 | 1. 性状:无色液体。 2. 密度(g/mL,25/4℃): 0.969 3. 相对蒸汽密度(g/mL,空气=1):未确定 4. 熔点(ºC): 未确定 5. 沸点(ºC,常压): 145~147 6. 沸点(ºC,5.2kPa):未确定 7. 折射率: 1.3840 8. 闪点(ºC): 23 9. 比旋光度(º):未确定 10. 自燃点或引燃温度(ºC):未确定 11. 蒸气压(kPa,25ºC):未确定 12. 饱和蒸气压(kPa,60ºC):未确定 13. 燃烧热(KJ/mol):未确定 14. 临界温度(ºC):未确定 15. 临界压力(KPa):未确定 16. 油水(辛醇/水)分配系数的对数值:未确定 17. 爆炸上限(%,V/V):未确定 18. 爆炸下限(%,V/V):未确定 19. 溶解性:未确定。 |
Synonym:BSTF Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.Moisture sensitive.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: No information regarding eye irritation and other potential effects was found. Skin: No information regarding skin irritation and other potential effects was found. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: The toxicological properties of this substance have not been fully investigated. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor. Extinguishing Media: Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Appearance: clear, colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 45.0 - 50.0 deg C @ Freezing/Melting Point: -10 deg C Autoignition Temperature: > 300 deg C (> 572.00 deg F) Flash Point: 43 deg C ( 109.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: hydrolysis Specific Gravity/Density: .9690g/cm3 Molecular Formula: CF3C=NSi(CH3)3OSi(CH3)3 Molecular Weight: 257.39 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, excess heat, electrical sparks. Incompatibilities with Other Materials: Strong oxidizing agents, strong acids. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride, nitrogen, silicon oxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 25561-30-2 unlisted. LD50/LC50: Not available. Carcinogenicity: Bis(trimethylsilyl)trifluoroacetamide, packaged in 1 ml ampules - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, N.O.S.* Hazard Class: 3 UN Number: 1993 Packing Group: III IMO Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3.3 UN Number: 1993 Packing Group: III RID/ADR Shipping Name: FLAMMABLE LIQUID, N.O.S. Dangerous Goods Code: 3(31C) UN Number: 1993 Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 10 Flammable. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 25561-30-2: No information available. United Kingdom Occupational Exposure Limits Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 25561-30-2 is not listed on Canada's Ingredient Disclosure List. Exposure Limits US FEDERAL TSCA CAS# 25561-30-2 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
毒理学数据: 主要的刺激性影响: 在皮肤上面: 在皮肤和粘膜上造成腐蚀性影响 刺激皮肤和粘膜 在眼睛上面: 强烈的腐蚀性影响 刺激的影响 致敏作用:没有已知的敏化作用。 生态学数据: 对水是稍微危害的,若无政府许可,勿将材料排入周围环境
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符号 |
GHS02, GHS05 |
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信号词 | Danger |
危害声明 | H226-H314 |
补充危害声明 | Corrosive to the respiratory tract., Reacts violently with water. |
警示性声明 | P280-P305 + P351 + P338-P310 |
个人防护装备 | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
危害码 (欧洲) | C:Corrosive |
风险声明 (欧洲) | R10;R34 |
安全声明 (欧洲) | S26-S36/37/39-S45-S16 |
危险品运输编码 | UN 2924 3/PG 3 |
WGK德国 | 3 |
包装等级 | III |
危险类别 | 3 |
海关编码 | 29310095 |
~% 25561-30-2 |
文献:Chemische Berichte, , vol. 103, p. 553 - 560 |
~% 25561-30-2 |
文献:Chemische Berichte, , vol. 109, p. 2542 - 2546 |
上游产品 4 | |
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下游产品 10 | |
海关编码 | 2931900090 |
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中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |