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16883-61-7

16883-61-7 structure
16883-61-7 structure
  • Name: Trimethylsilyl 2-methylpropanoate
  • Chemical Name: trimethylsilyl 2-methylpropanoate
  • CAS Number: 16883-61-7
  • Molecular Formula: C7H16O2Si
  • Molecular Weight: 160.286
  • Create Date: 2018-08-06 12:08:22
  • Modify Date: 2024-01-09 22:29:26

Name trimethylsilyl 2-methylpropanoate
Synonyms Isobuttersaeure-trimethylsilylester
isobutyric acid trimethylsilanyl ester
Propanoic acid, 2-methyl-, trimethylsilyl ester
2-methylpropionic acid trimethylsilylester
Trimethylsilyl isobutyrate
trimethylsilyl 2-methylpropionate
Isobutyryloxy-trimethyl-silan
Isobutyric acid, trimethylsilyl ester
Isobutyric acid,trimethylsilyl ester
MFCD01632553
Trimethyl-isobutyryloxy-silan
Trimethylsilyl 2-methylpropanoate
Density 0.9±0.1 g/cm3
Boiling Point 134.2±9.0 °C at 760 mmHg
Molecular Formula C7H16O2Si
Molecular Weight 160.286
Flash Point 29.2±14.3 °C
Exact Mass 160.091949
PSA 26.30000
LogP 2.11
Vapour Pressure 8.2±0.2 mmHg at 25°C
Index of Refraction 1.404
Name: TRIMETHYLSILYL ISOBUTYRATE Material Safety Data Sheet
Synonym:
CAS: 16883-61-7
Section 1 - Chemical Product MSDS Name:TRIMETHYLSILYL ISOBUTYRATE Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
16883-61-7 TRIMETHYLSILYL ISOBUTYRATE unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16883-61-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 132 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 160.29

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 16883-61-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
TRIMETHYLSILYL ISOBUTYRATE - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 16883-61-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16883-61-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16883-61-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S24/25
HS Code 2931900090

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Literature: Journal of Organic Chemistry, , vol. 47, # 15 p. 2900 - 2903

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Literature: Journal of Organometallic Chemistry, , vol. 46, p. 73 - 87

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Literature: Central European Journal of Chemistry, , vol. 9, # 5 p. 813 - 824

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Literature: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 528 Chem.Abstr., , # 6298

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Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 50, # 5 p. 1059 - 1064,851 - 855
HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%