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乙酸异辛酯

乙酸异辛酯用途

【主要用途】

用于有机合成。

乙酸异辛酯名称

[ CAS 号 ]:
103-09-3

[ 中文名 ]:
醋酸-2-乙基己酯

[ 英文名 ]:
2-ethylhexyl acetate

[中文别名 ]:

[英文别名 ]:

2-Ethyl-1-hexanol acetate
β-ethylhexyl acetate
2-ethylhexylacetate
Acetic Acid 2-Ethylhexyl Ester
2-Ethylhexyl acetate
Acetic acid,2-ethylhexyl ester
2-Ethylhexanyl acetate
2-Ethyl-1-hexyl acetate
2-ethylhexan-1-ol acetate
2-Ethylhexyl ethanoate

乙酸异辛酯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
195.7±8.0 °C at 760 mmHg

[ 熔点 ]:
−92 °C(lit.)

[ 分子式 ]:
C₁₀H₂₀O₂

[ 分子量 ]:
172.265

[ 闪点 ]:
71.4±8.3 °C

[ 精确质量 ]:
172.146332

[ PSA ]:
26.30000

[ LogP ]:
3.71

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
0.4±0.4 mmHg at 25°C

[ 折射率 ]:
1.421

[ 储存条件 ]:
库房通风低温干燥

[ 水溶解性 ]:
水溶性：微溶；混溶：醇,乙醚

乙酸异辛酯MSDS

乙酸异辛酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AH5600000

CHEMICAL NAME :: Acetic acid, 2-ethylhexyl ester

CAS REGISTRY NUMBER :: 103-09-3

BEILSTEIN REFERENCE NO. :: 1758321

LAST UPDATED :: 199710

DATA ITEMS CITED :: 15

MOLECULAR FORMULA :: C10-H20-O2

MOLECULAR WEIGHT :: 172.30

WISWESSER LINE NOTATION :: 4Y2&1OV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 26,269,1944

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 4/21/1967

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AJOPAA American Journal of Ophthalmology. (Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611) Series 3: V.1- 1918- Volume(issue)/page/year: 29,1363,1946

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,361,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 26,269,1944

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >1100 ppm/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >3200 mg/kg

TOXIC EFFECTS :: Toxic effects not yet reviewed

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21May1971

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >20 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 4/21/1967

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: >20 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 26,269,1944 *** REVIEWS *** TOXICOLOGY REVIEW CHREAY Chemical Reviews. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1924- Volume(issue)/page/year: 48,225,1951 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2386 No. of Facilities: 114 (estimated) No. of Industries: 3 No. of Occupations: 7 No. of Employees: 1013 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2386 No. of Facilities: 1596 (estimated) No. of Industries: 21 No. of Occupations: 28 No. of Employees: 20380 (estimated) No. of Female Employees: 4167 (estimated)

乙酸异辛酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ WGK德国 ]:
1

[ RTECS号 ]:
AH5600000

[ 海关编码 ]:
29153990

乙酸异辛酯合成路线

乙酸异辛酯上下游产品

乙酸异辛酯上游产品

乙酸异辛酯下游产品

乙酸异辛酯制备

精制方法：含有游离的酸和醇等杂质。精制时用碳酸氢钠或碳酸钠水溶液洗涤，无水碳酸钠或硫酸钠干燥后精馏。

乙酸异辛酯海关

[ 海关编码 ]: 2915390090

[ 中文概述 ]:
2915390090. 其他乙酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

乙酸异辛酯文献

Efficient hydrolytic reaction of an acetate ester with fungal lipase in a liquid-liquid interface bioreactor (L-L IBR) using CaCO₃-coated ballooned microsphere.

J. Biosci. Bioeng. 112(2) , 151-3, (2011)

In a liquid-liquid interface bioreactor using a CaCO₃-coated ballooned microsphere, 2-ethylhexyl acetate was efficiently hydrolyzed to 2-ethyl-1-hexanol with Absidia coerulea NBRC 4423 compared with u...

Microencapsulation of pheromone-analogue and measurement of the sustained release.

J. Microencapsul. 8(4) , 465-78, (1991)

A model study was conducted to establish 2 feasible production and application systems for the long-term, sustained release of pheromone into the atmosphere of targeted areas. The desired goal of effe...

Reactive chromatography for the synthesis of 2-ethylhexyl acetate. Gyani VC and Mahajani S.

Sep. Sci. Technol. 43(9-10) , 2245-2268, (2008)

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