Oxidations by methyl (trifluoromethyl) dioxirane. 2. Oxyfunctionalization of saturated hydrocarbons

R Mello, M Fiorentino, C Fusco…

文献索引：Mello, Rossella; Fiorentino, Michele; Fusco, Caterina; Curci, Ruggero Journal of the American Chemical Society, 1989 , vol. 111, # 17 p. 6749 - 6757

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被引用次数: 271

摘要

Abstract: The reaction of methyl (trifluoromethy1) dioxirane (lb), a novel dioxirane species, with two open-chain, four cyclic, and five polycyclic saturated hydrocarbons and two aralkyl hydrocarbons in CH, C12/1, l, I-trifluoropropanone has been studied; under mild conditions (- 22 to 0" C), it gives alcohols and/or ketones (deriving from further oxidation of secondary alcohols) in high yields and within very short reaction times. Primary CH bonds are not ...