The iron (II) complex [Fe (CF3SO3) 2 (mcp)] as a convenient, readily available catalyst for the selective oxidation of methylenic sites in alkanes

…, L Gómez Martín, X Ribas Salamaña…

文献索引：Canta, Merce; Font, David; Gomez, Laura; Ribas, Xavi; Costas, Miquel Advanced Synthesis and Catalysis, 2014 , vol. 356, # 4 p. 818 - 830

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摘要

Resum The efficient and selective oxidation of secondary CH sites of alkanes is achieved by using low catalyst loadings of a non-expensive, readily available iron catalyst [Fe (II)(CF3SO3) 2 (mcp)],{Fe-mcp,[mcp= N, N'-dimethyl-N, N'-bis (2-pyridylmethyl) cyclohexane- trans-1, 2-diamine]}, and hydrogen peroxide (H2O2) as oxidant, via a simple...[+]