Réaction non classique au cours de l′ alkylation des Halogénures d′ éments de la colonne IVB par des Réactifs de Grignard; cas du t′ trachlorure de silicium
F Métras, JC Lahournène, J Valade
文献索引：Metras,F. et al. Journal of Organometallic Chemistry, 1971 , vol. 29, p. 41 - 60
Abstract The reaction of sterically hindered Grignanrd reagents with silicon tetrachloride leads before hydrolysis to important yields of dialkylmonochlorosilanes. The formation of such compounds results from the reduction of SiCl 4 to HSiCl 3 followed by alkylation with the Grignard reagent. The different steps of these transformations are proved by chemical and physicochemical ways.
