Acta Chemica Scandinavica

Mechanism of the Grignard Addition Reaction. XVI. Homolytic and Concerted Mechanisms in the Reaction of a, ß-Unsaturated Carbonyl Compounds with …

T Holm

文献索引：Holm, Torkil Acta Chemica Scandinavica, 1991 , vol. 45, # 9 p. 925 - 929

全文：HTML全文

被引用次数: 18

摘要

Kinetic measurements have shown that the addition of Grignard reagents to a, ßunsaturated carbonyl compounds takes place either by a concerted mechanism or by a homolytic mechanism. Phenylmagnesium bromide, which is incapable of homolysis, reacts rapidly in a