Organocopper chemistry. Halo-, cyano-, and carbonyl-substituted ketones from the corresponding acyl chlorides and organocopper reagents

GH Posner, CE Whitten…

文献索引：Posner,G.H. et al. Journal of the American Chemical Society, 1972 , vol. 94, p. 5106 - 5108

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被引用次数: 94

摘要

Organic chemists are continually seeking new reagents for specific and mild formation of carbon-carbon bonds. Organocopper reagents are now becoming widely used in conjugate addition reactions with a, p-unsaturated carbonyl substrates and in coupling reactions with organic halides. We have recently reported formation of methyl and n-alkyl ketones from carboxylic acid chlorides and lithium diorganocuprate (1) reagents, and now we describe ...