Reactions of alkenes with ozone in the gas phase: a matrix-isolation study of secondary ozonides and carbonyl-containing reaction products

…, MJ Almond, G Marston, VP Ly, KS Wiltshire

文献索引：Feltham, Emma J.; Almond, Matthew J.; Marston, George; Ly, Vivienne P.; Wiltshire, Karen S. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2000 , vol. 56, # 13 p. 2605 - 2616

全文：HTML全文

被引用次数: 34

摘要

Gas phase ozonolysis reactions of the alkenes ethene, cis-and trans-but-2-ene, isoprene and the monoterpenes α-pinene, β-pinene, 3-carene, limonene and β-myrcene have been carried out and the reaction products have been trapped in O2-doped-argon matrices onto a CsI window held at 12 K. Products have been identified by IR spectroscopy. Comparison with previous matrix spectra, where secondary ozonides have been generated either in ...