The mechanism of ozone-alkene reactions in the gas phase. A mass spectrometric study of the reactions of eight linear and branched-chain alkenes

RI Martinez, JT Herron, RE Huie

文献索引：Martinez, Richard I.; Herron, John T.; Huie, Robert E. Journal of the American Chemical Society, 1981 , vol. 103, # 13 p. 3807 - 3820

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被引用次数: 98

摘要

Abstract: The stable products of the low-pressure (4-8 torr (1 torr= 133.33 Pa)) gas-phase reactions of ozone with ethene, propene, 2-methylpropene, cis-2-butene, trans-2-butene, trans-2-pentene, 2, 3-dimethyl-2-butene, and 2-ethyl-1-butene have been identified by using a photoionization mass spectrometer coupled to a stirred-flow reactor. The products observed are characteristic of (i) a primary Criegee split to an oxoalkane (aldehyde or ...