Mechanism of the ozonolysis of ethylene in the liquid phase

GD Fong, RL Kuczkowski

文献索引：Fong, Gerald D.; Kuczkowski, Robert L. Journal of the American Chemical Society, 1980 , vol. 102, # 14 p. 4763 - 4768

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被引用次数: 22

摘要

Abstract: The ozonolysis of ethylene to ethylene ozonide was studied in a variety of solvents. The cross-ozonide yields, aldehyde-insertion yields, secondary kinetic isotope effects, and reaction stereochemistry were evaluated by using mass spectroscopy and microwave spectroscopy to follow isotopic labels. Yields of ozonide are high and can be maximized with polar solvents and low temperatures. Cross-ozonide and aldehyde-insertion yields ...