The ozonolysis of ethylene. Microwave spectrum, molecular structure, and dipole moment of ethylene primary ozonide (1, 2, 3-trioxolane)

JZ Gillies, CW Gillies, RD Suenram…

文献索引：Gillies, J. Z.; Gillies, C. W.; Suenram, R. D.; Lovas, F. J. Journal of the American Chemical Society, 1988 , vol. 110, # 24 p. 7991 - 7999

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被引用次数: 56

摘要

Abstract: The gas-phase structure of ethylene primary ozonide (CH2CH2000) has been determined from millimeter wave spectra of five isotopic species. Partial substitution, r,, parameters for the lowest energy oxygen envelope conformation (C, symmetry) are r (CC)= 1.546 (3) A, r (C0)= 1.417 (10) A, r (O0)= 1.453 (10) A, r (CHcodo)= 1.088 (5) A, r (CHo,)=