Nonlinear Taft Polar Free Energy Relationship: Reactions of N??Substituted Benzyl Amines with Benzyl Bromide in Methanol

…, R Sanjeev, V Jagannadham

文献索引：Ravi; Sanjeev; Jagannadham International Journal of Chemical Kinetics, 2013 , vol. 45, # 12 p. 803 - 810

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被引用次数: 6

摘要

ABSTRACT The rates of reactions of N-substituted benzyl amines with benzyl bromide were measured using a conductivity technique in methanol medium. The reaction followed a total second-order path. The end product of the reaction is identified as dibenzyl alkyl amine (C 6 H 5 CH 2 N (R) CH 2 C 6 H 5). The rates increased with a decrease in the electron-donating capacity or with an increase in the Taft σ* value of electron-donating alkyl substituents (R) ...