N-alkylation of amines by homogeneous ruthenium complexes in the presence of free diphosphines

B Tamaddoni Jahromi, AN Kharat

文献索引：Tamaddoni Jahromi, Bahareh; Kharat, Ali Nemati Journal of Coordination Chemistry, 2013 , vol. 66, # 19 p. 3498 - 3508

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被引用次数: 1

摘要

Chemoselective N-alkylation of amines by ruthenium complexes in the presence of free diphosphine ligands under mild conditions is described. Octyl amine and aniline were chosen as aliphatic and aromatic amines to investigate the effect of different phosphines, reaction times, and temperature on conversion, as well as selectivity towards related secondary and tertiary amines. After optimization of the reaction conditions, this catalytic ...