ChemCatChem

A Highly Active Cationic Ruthenium Complex for Alkene Isomerisation: A Catalyst for the Synthesis of High Value Molecules

S Manzini, DJ Nelson, SP Nolan

文献索引：Manzini, Simone; Nelson, David J.; Nolan, Steven P. ChemCatChem, 2013 , vol. 5, # 10 p. 2848 - 2851

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被引用次数: 15

摘要

The isomerisation of terminal alkenes to form internal alkenes is an extremely useful process, employed in industrial processes to equilibrate feedstocks or to achieve high-value molecules starting from easily accessible precursors. Moreover, this transformation is also widely applied in synthetic chemistry;[1] in particular, this can be used to obtain vinyl derivatives staring from the corresponding allylic moiety, which can often be easier to ...