前往化源商城

Tetrahedron letters

Selective deprotective method using palladium-water soluble catalysts

S Lemaire-Audoire, M Savignac, E Blart, G Pourcelot…

文献索引:Lemaire-Audoire; Lemaire-Audoire, Sandrine; Savignac; Savignac, Monique; Blart; Blart, Errol; Pourcelot; Pourcelot, Guy; Genet; Genet, Jean Pierre; Bernard; Bernard, Jean-Marie Tetrahedron Letters, 1994 , vol. 35, # 47 p. 8783 - 8786

全文:HTML全文

被引用次数: 55

摘要

Abstract Allylcarboxy and Allyloxycarbonyl groups can be removed without affecting dimethylallylcarboxy and cinnamylcarboxy groups in the same molecule, using Pd (0) water soluble catalyst prepared in situ, with diethylamine as allyl scavenger. Homogeneous or biphasic media are suitable; the yields of deprotection are quantitative.