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THE REACTION BETWEEN SULFOCHLORIDES AND ORGANOMAGNESIUM HALIDES

H Gilman, RE Fothergill

文献索引:Gilman; Fothergill Journal of the American Chemical Society, 1929 , vol. 51, p. 3506

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被引用次数: 21

摘要

Tetra-ethylphosphonium iodide and sodium triphenylmethyl give at once colorless products and the reaction is apparently analogous to that between alkali metal alkyls and quaternary ammonium salts. Triphenylalkylphosphonium halides react with alkali metal alkyls to give colored products, apparently identical with the phosphinemethylenes of Staudinger, as the primary products of the reaction. The products isolated from several different reactions of ...