THE REACTION BETWEEN SULFOCHLORIDES AND ORGANOMAGNESIUM HALIDES

H Gilman, RE Fothergill

Index: Gilman; Fothergill Journal of the American Chemical Society, 1929 , vol. 51, p. 3506

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Citation Number: 21

Abstract

Tetra-ethylphosphonium iodide and sodium triphenylmethyl give at once colorless products and the reaction is apparently analogous to that between alkali metal alkyls and quaternary ammonium salts. Triphenylalkylphosphonium halides react with alkali metal alkyls to give colored products, apparently identical with the phosphinemethylenes of Staudinger, as the primary products of the reaction. The products isolated from several different reactions of ...