Mechanisms of hemin-catalyzed oxidations: rearrangements during the epoxidation of trans-cyclooctene

TG Traylor, Y Iamamoto, T Nakano

文献索引：Traylor, Teddy G.; Iamamoto, Yassuko; Nakano, Taku Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3529 - 3531

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被引用次数: 43

摘要

RH'+-R'+ H+(8) tron-transfer oxidation of strained alkanes by electrochemical methods and by photoexcited electron acceptors is well-known." The most recent work on the stoichiometric oxidation of alkanes by ColI1 and related species at elevated temperatures, however, suggests that these processes probably do not involve electrontransfer oxidation of the alkane. I2* l3 Whereas the regiochemistry is likely determined by eq 7 and 8, the ...