Journal of the American Chemical Society

Photochemical Reactions. X. 1, 2 Experiments with 1, 3, 5-Cycloöctatrien-7-one and Cycloöctatetraene Epoxide

G Buchi, EM Burgess

文献索引：Buechi,G.; Burgess,E.M. Journal of the American Chemical Society, 1962 , vol. 84, p. 3104 - 3109

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被引用次数: 30

摘要

Irradiation of 1, 3, 5-cyclooctatrien-7-one in hexane solution yielded bicyclo [4.2. 0] octa-4, 7- dien-2-one. The anticipated bicyclo [2.2. 2] octadienone was not detected. On exposure to ultraviolet light in methanol solution the monocyclic ketone was transformed to a methyl octa- 1, 3, 5-trienoate of unknown configuration which on subsequent equilibration was partly converted to the known trans-tvans-ester. Pyrolysis of cyclooctatrienone and its ...