Synthetic Communications

Expedient Method for Oxidation of Alcohol by Hydrogen Peroxide in the Presence of Amberlite IRA 400 Resin (Basic) as Phase??Transfer Catalyst

N Bhati, K Sarma, A Goswami

文献索引：Bhati, Nishi; Sarma, Kuladip; Goswami, Amrit Synthetic Communications, 2008 , vol. 38, # 9 p. 1416 - 1424

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被引用次数: 9

摘要

Abstract Amberlite IRA 400 (strongly basic), a classical polymer imparts phase??transfer catalysis in the oxidation of primary and secondary alcohols by hydrogen peroxide to give excellent yields of the corresponding carbonyl compounds or carboxylic acids in acetonitrile solvent at reflux temperature in 4–6 h. The catalytic system is inert to other susceptible oxidation sites such as carbon–carbon double bonds