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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Oxidative decyanation of secondary nitriles to ketones

RW Freerksen, SJ Selikson, RR Wroble…

文献索引：Freerksen, Robert W.; Selikson, Sandra J.; Wroble, Randall R.; Kyler, S. Keith; Watt, David S. Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4087 - 4096

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被引用次数: 49

摘要

Procedures for the oxidative decyanation of secondary nitriles to ketones involve (1) iodination of N-(trialkylsily1) ketenimines derived from secondary nitriles and subsequent hydrolysis of the dodo nitriles with silver oxide,(2) addition of nitrosobenzene to N- (trialkylsilyl) ketenimines,(3) conversion of secondary nitriles to a-(phenylthio) nitriles and subsequent hydrolysis with N-bromosuccinimide in aqueous acetonitrile, and (4) ...

(1-氰基乙基)膦酸二乙酯结构式

(1-氰基乙基)膦酸二乙酯

环十二酮结构式

~92%

2-cyclododecylidenepropanenitrile结构式

2-cyclododecyli...

2-(10,13-dimethyl-1,2,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydrospiro[cyclopenta[a]phenanthrene-3,2'-[1,3]dioxolan]-17-yl)propanenitrile结构式

2-(10,13-dimeth...

~%

Pregn-5-ene-3,20-dione(6CI,7CI,8CI,9CI)结构式

Pregn-5-ene-3,2...

氰化钠结构式

2-溴辛烷结构式

~70%

2-methyloctanenitrile结构式

2-methyloctanen...

2-(4-甲氧基苯基)-2-苯基乙腈结构式

2-(4-甲氧基苯基)-2-苯基乙腈

~90%

4-甲氧基二苯甲酮结构式

4-甲氧基二苯甲酮

未登录结构式

~%

5-苯基戊烷-2-酮结构式

5-苯基戊烷-2-酮

1-溴-3-苯基丙烷结构式

1-溴-3-苯基丙烷

~%

5-苯基戊烷-2-酮结构式

5-苯基戊烷-2-酮

2-溴丁酰胺结构式

~78%

2-溴丁腈结构式

2-bromo-3-methyl-butanamide结构式

2-bromo-3-methy...

~%

2-diethoxyphosphoryl-3-methylbutanenitrile结构式

2-diethoxyphosp...

2-bromo-3-methylbutanenitrile结构式

2-bromo-3-methy...

亚磷酸三乙酯结构式

亚磷酸三乙酯

~40%

2-diethoxyphosphoryl-3-methylbutanenitrile结构式

2-diethoxyphosp...

异戊酸结构式

~31%

2-bromo-3-methyl-butanamide结构式

2-bromo-3-methy...

2,5-diphenylvaleronitrile结构式

2,5-diphenylval...

~%

1,4-联苯基-1-丁酮结构式

1,4-联苯基-1-丁酮

1-溴-3-苯基丙烷结构式

1-溴-3-苯基丙烷

~%

1,4-联苯基-1-丁酮结构式

1,4-联苯基-1-丁酮

苯乙腈结构式

~%

1,4-联苯基-1-丁酮结构式

1,4-联苯基-1-丁酮

2-phenyl-cyclohex-3-enecarbonitrile结构式

2-phenyl-cycloh...

~%

2-phenylcyclohex-2-en-1-one结构式

2-phenylcyclohe...

1-苯-1,3-丁二烯结构式

1-苯-1,3-丁二烯

~%

2-phenylcyclohex-2-en-1-one结构式

2-phenylcyclohe...

正丁酸结构式

~48%

2-溴丁酰胺结构式