Mechanisms of epoxidations and chlorinations of hydrocarbons by inorganic hypochlorite in the presence of a phase-transfer catalyst

…, S Krishnan, DG Kuhn, GA Hamilton

文献索引：Fonouni; Krishnan; Kuhn; Hamilton Journal of the American Chemical Society, 1983 , vol. 105, # 26 p. 7672 - 7676

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被引用次数: 42

摘要

Abstract: Inorganic hypochlorite in the presence of a quaternary ammonium salt (phase- transfer catalyst) not only epoxidizes several arenes to arene oxides in high yields but also converts toluene to a-chlorotoluene, anisole to ring chlorinated anisoles, and alkenes to a complex mixture of chlorinated and oxidized products, including the epoxide. More detailed studies with this system indicate the following:(1) the high-yield conversion of toluenes to ...