Decomposition of Tertiary Alkyl Hypochlorites1

FD Greene, ML Savitz, FD Osterholtz…

文献索引：Greene,F.D. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 55 - 64

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被引用次数: 91

摘要

Results The hypochlorites were prepared by the action of hypochlorous acid on the alcohols. The decompositions were effected thermally or photochemically in Freon 11 ( trichlorofluoromethane), carbon tetrachloride, or cyclohexene. Products were isolated by gas phase chromatography. In most cases an account'ing is made for SO-SO% of the hypochlorite.(Decompo-(1)(a) For a preliminary account of work in this area, see FD ...