Journal of the American Chemical Society

A Free-Radical 1, 2-Vinyl Migration

LH Slaugh

文献索引：Slaugh,L.H. Journal of the American Chemical Society, 1965 , vol. 87, p. 1522 - 1526

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被引用次数: 17

摘要

Wilt and Levins experienced considerable difficulty in their attempts to decarbonylate unsaturated aldehydes, such as cyclohexene-4-carboxaldehyde. Consequently, radicals I and I1 were generated by heating (140") dilute solutions of t-butyl cyclohexene-4- peroxycarboxylate (111) and t-butyl A,-cyclopentenylperoxyacetate (IV), respectively. In general, the experimental