Factors influencing conformational preferences in cyclohexenes

JB Lambert, DE Marko

文献索引：Lambert, Joseph B.; Marko, Dale E. Journal of the American Chemical Society, 1985 , vol. 107, # 26 p. 7978 - 7982

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被引用次数: 33

摘要

Abstract: Conformational preferences have been measured for the first time for 4-substituted cyclohexenes in a solvent of low polarity. Measurements were made for the substituents C1, Br, I, OH, OSiMe,, and CN and were compared with conformational preferences in cyclohexyl and exo-methylenecyclohex-3-yl. In the nearly nonpolar solvent CFZCI2, in which intramolecular interactions are maximized, there is a much larger axial population for ...